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The diagram below represents a complex series of chemical reactions that take place when the polymer degrades in the presence of oxygen and how antioxidants can intervene in this process. Primary antioxidants (phenolics) and secondary antioxidants (phosphites, also known as processing stabilizers) thus play an important role in counteracting

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Antioxidants. Polymers will change over time when exposed to radiation, excessive heat and/or corrosive enviroments. These changes are the result of oxidative degradation caused by free radicals which form through hydrogen abstration or homolytic scission of carbon-carbon bonds when polymers are exposed to heat, oxygen, ozone, or light.

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